Bulk Metal-Organics and Silanes: Pharmaceutical & Organic Synthesis

Metal-organics and silanes that can be used as cross-coupling reagents, silane reducing agents, silane blocking agents, aluminum alkyls, and metal esters. This guide provides physical properties and information on synthetic applications of silanes that facilitate selection of readily available commercial materials.

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Aluminum-based

Aluminum-based Metal-Organics

SKU	Image	Name
AKA020		ALUMINUM s-BUTOXIDE
AKA070		ALUMINUM ISOPROPOXIDE
OMAL021.2		DIISOBUTYLALUMINUM HYDRIDE, 1M in heptane (19-20 wt%)
OMAL021.5		DIISOBUTYLALUMINUM HYDRIDE, 0.85M in tetrahydrofuran (14-16 wt%)
OMAL021.7		DIISOBUTYLALUMINUM HYDRIDE, 1M in toluene (16-17 wt%)
OMAL024.2		DIMETHYLALUMINUM CHLORIDE, 1M in heptane (12-14 wt %)
OMAL033.2		ETHYLALUMINUM DICHLORIDE, 1M in heptane (16-18 wt%)
OMAL033.7		ETHYLALUMINUM DICHLORIDE, 1.8M in toluene (24-26 wt%)
OMAL082.2		TRIISOBUTYLALUMINUM, 0.7M in heptane (19-21 wt%)
OMAL082.7		TRIISOBUTYLALUMINUM, 25% in toluene
OMAL086.2		TRIMETHYLALUMINUM, 1M in heptane (10-11 wt%)
OMAL086.4		TRIMETHYLALUMINUM, 2M in toluene (17-18 wt%)

Boron-based

Boron-based Metal-Organics

SKU	Image	Name
AKB156.5		BORON ISOPROPOXIDE
AKB157		BORON METHOXIDE

Copper-based

Copper-based Metal-Organics

SKU	Image	Name
CXCU010		COPPER(II) ACETATE, monohydrate
AKC260		COPPER(II) 2,4-PENTANEDIONATE

Lithium-based

Lithium-based Metal-Organics

SKU	Image	Name
OMLI012		n-BUTYLLITHIUM, 2.5M in hexanes (22-24 wt %)
SIL6467.2		LITHIUM HEXAMETHYLDISILAZIDE, 0.85M in hexane (19-21 wt %)
SIL6467.4		LITHIUM HEXAMETHYLDISILAZIDE 1M in tetrahydrofuran
AKL461		LITHIUM METHOXIDE, 2.25M in methanol (9-10 wt %)
OMLI041		DISC. SIZE METHYL LITHIUM, 3M in diethoxymethane, (7-9 wt %)

Magnesium-based

Magnesium-based Metal-Organics

SKU	Image	Name
AKM503		MAGNESIUM METHOXIDE, 7-8% in methanol

Phosphorus-based

Phosphorus-based Metal-Organics

SKU	Image	Name
OMFE022		1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
OMPH027		DIETHYLPHOSPHITE
OMPH056		DIPHENYLPHOSPHORYL AZIDE
OMPH081		TRIPHENYLPHOSPHINE OXIDE
OMPH081.4		TRI(o-TOLYL)PHOSPHINE

Potassium-based

Potassium-based Metal-Organics

SKU	Image	Name
CXPO010		POTASSIUM ACETATE
AKP630		POTASSIUM t-BUTOXIDE
AKP632		POTASSIUM t-BUTOXIDE, 1.6M in tetrahydrofuran (19-20 wt%)
SIP6890.0		POTASSIUM HEXAMETHYLDISILAZIDE, 11% in toluene, 0.5M
SIP6890.1		POTASSIUM HEXAMETHYLDISILAZIDE, 20% in THF
AKP643		POTASSIUM ISOPROPOXIDE, 18 - 20% in isopropanol
AKP645		POTASSIUM METHOXIDE, 95%
AKP646		POTASSIUM METHOXIDE, 3.4M
AKP647		POTASSIUM 2-METHYL-2-BUTOXIDE, 96%
AKP648		POTASSIUM 2-METHYL-2-BUTOXIDE, 14-16% in cyclohexane
SIP6901.2		POTASSIUM TRIMETHYLSILANOLATE, 2M in tetrahydrofuran (26-29 wt %)

Silicon-based

Silicon-based Metal-Organics

SKU	Image	Name
SIA0540.0		ALLYLTRIMETHOXYSILANE
SIA0555.0		ALLYLTRIMETHYLSILANE
SIB1844.0		BIS(TRIMETHYLSILOXY)METHYLSILANE
SIB1846.0		N,O-BIS(TRIMETHYLSILYL)ACETAMIDE
SIB1876.0		N,O-BIS(TRIMETHYLSILYL)TRIFLUOROACETAMIDE
SIB1878.0		N,N'-BIS(TRIMETHYLSILYL)UREA
SIB1935.0		t-BUTYLDIMETHYLCHLOROSILANE
SIB1935.2		t-BUTYLDIMETHYLCHLOROSILANE, 1.0M in methylene chloride
SIB1935.4		t-BUTYLDIMETHYLCHLOROSILANE, 3M in tetrahydrofuran
SIB1935.5		t-BUTYLDIMETHYLCHLOROSILANE, 2.85M in toluene, 48-52% solution
SIB1968.0		t-BUTYLDIPHENYLCHLOROSILANE
SIB1977.0		n-BUTYL-1,1,3,3-TETRAMETHYLDISILOXANE
SIC2285.0		CHLOROMETHYLDIMETHYLCHLOROSILANE
SIC2305.0		CHLOROMETHYLTRIMETHYLSILANE, 97%
SID2650.0		DECAMETHYLCYCLOPENTASILOXANE
SID3372.0		1,3-DICHLOROTETRAMETHYLDISILOXANE
SID3398.0		(DIETHYLAMINO)TRIMETHYLSILANE
SID3537.0		DIISOPROPYLDICHLOROSILANE
SID3605.0		(N,N-DIMETHYLAMINO)TRIMETHYLSILANE
SID4070.0		DIMETHYLCHLOROSILANE, 98%
SID4120.0		DIMETHYLDICHLOROSILANE, 98%
SID4120.1		DIMETHYLDICHLOROSILANE, 99+%
SID4552.0		DIPHENYLMETHYLCHLOROSILANE
SID4613.0		1,3-DIVINYLTETRAMETHYLDISILOXANE
SIE4904.0		ETHYNYLTRIMETHYLSILANE, 97%
SIH5843.0		HEPTAMETHYLDISILAZANE
SIH6105.0		HEXAMETHYLCYCLOTRISILOXANE
SIH6109.0		HEXAMETHYLDISILANE
SIH6110.0		1,1,1,3,3,3-HEXAMETHYLDISILAZANE, 98%
SIH6110.1		1,1,1,3,3,3-HEXAMETHYLDISILAZANE, 99%
SIH6115.0		HEXAMETHYLDISILOXANE, 98%
SIH6115.1		HEXAMETHYLDISILOXANE, 99.9%
SIH6117.0		1,1,3,3,5,5-HEXAMETHYLTRISILOXANE
SIL6467.2		LITHIUM HEXAMETHYLDISILAZIDE, 0.85M in hexane (19-21 wt %)
SIL6467.4		LITHIUM HEXAMETHYLDISILAZIDE 1M in tetrahydrofuran
SIM6510.0		METHYLHYDROCYCLOSILOXANES, 92%
SIO6620.0		OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE, 60% in methanol
SIP6728.0		PHENYLDIMETHYLCHLOROSILANE
SIP6821.0		PHENYLTRIETHOXYSILANE
SIP6822.0		PHENYLTRIMETHOXYSILANE
SIP6890.0		POTASSIUM HEXAMETHYLDISILAZIDE, 11% in toluene, 0.5M
SIP6890.1		POTASSIUM HEXAMETHYLDISILAZIDE, 20% in THF
SIS6980.2		SODIUM BIS(TRIMETHYLSILYL)AMIDE, 2M in tetrahydrofuran
SIS6985.0		SODIUM MONTMORILLONITE CLAY
SIT7273.0		1,1,3,3-TETRAISOPROPYL-1,3-DICHLORODISILOXANE
SIT7546.0		1,1,3,3-TETRAMETHYLDISILOXANE, 98%
SIT8250.0		TRIETHYLCHLOROSILANE
SIT8330.0		TRIETHYLSILANE, 98%
SIT8335.0		TRIETHYLSILYLTRIFLUOROMETHANESULFONATE
SIT8510.0		TRIMETHYLCHLOROSILANE
SIT8510.1		TRIMETHYLCHLOROSILANE, 99+%
SIT8564.0		TRIMETHYLIODOSILANE
SIT8510.0		TRIMETHYLCHLOROSILANE
SIT8510.1		TRIMETHYLCHLOROSILANE, 99+%
SIT8564.0		TRIMETHYLIODOSILANE
SIT8580.0		TRIMETHYLSILYL AZIDE, 96%
SIT8585.0		TRIMETHYLSILYLCYANIDE
SIT8594.1		TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in methyltetrahydrofuran (46-48 wt %)
SIT8590.0		N-(TRIMETHYLSILYL)IMIDAZOLE
SIT8606.5		1-TRIMETHYLSILYLPROPYNE
SIT8620.0		TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE
SIT8720.0		TRIS(TRIMETHYLSILOXY)ETHYLENE, 92%
SIT8724.0		TRIS(TRIMETHYLSILYL)SILANE
SIV9070.0		VINYLDIMETHYLCHLOROSILANE
SIV9250.0		VINYLTRIMETHYLSILANE

Sodium-based

Sodium-based Metal-Organics

SKU	Image	Name
CXSO010		SODIUM ACETATE
SIS6980.2		SODIUM BIS(TRIMETHYLSILYL)AMIDE, 2M in tetrahydrofuran
AKS740		SODIUM ETHOXIDE. 95%
AKS741		SODIUM ETHOXIDE, 21% in ethanol
AKS751		SODIUM ISOPROPOXIDE 19-21% in tetrahydrofuran
AKS760		SODIUM METHOXIDE, 95%
AKS761		SODIUM METHOXIDE, 25% in methanol
AKS768.5		SODIUM 2-METHYL-2-BUTOXIDE, 35% in tetrahydrofuran

Tin-based

Tin-based Metal-Organics

SKU	Image	Name
SNA0500		ALLYLTRI-n-BUTYLTIN
SND3355		DI-n-BUTYLTIN SULFIDE, tech
SNE4620		1-ETHOXYVINYLTRI-n-BUTYLTIN
SNT7560		TETRAMETHYLTIN
SNT8085		TRI-n-BUTYLCHLOROTIN
SNT8130		TRI-n-BUTYLTIN HYDRIDE

Titanium-based

Titanium-based Metal-Organics

SKU	Image	Name
AKT851.1		TITANIUM CHLORIDE TRIISOPROPOXIDE, 2M in hexane (58 wt %)
AKT851.3		TITANIUM CHLORIDE TRIISOPROPOXIDE, 2M in heptane
AKT854.1		TITANIUM DICHLORIDE DIETHOXIDE, 1.5M in ethanol (30-32 wt %)
AKT872		TITANIUM ISOPROPOXIDE

Zinc-based

Zinc-based Metal-Organics

SKU	Image	Name
OMZN018		DIETHYLZINC, 1M in heptane (16-17 wt %)
CXZN085		ZINC UNDECYLENATE