Silicon-based reagents for functional group protection, synthetic transformation, and derivatization for gas chromatographic analyses. These materials can be the protection of alcohols, phenols, diols, amines, carboxylic acids, and thiols.
Contents:
- Silicon-Based Protecting Agents including the introduction of the silyl groups, consideration of byproducts, and the stability of silyl-protected functional groups
- Silyl Groups: trimethylsilyl (TMS), triethylsilyl (TES), tert-butyldimethylsilyl (TBS), thexyldimethylsilyl (TDS), tert-butyldiphenylsilyl (TBDPS), triisopropylsilyl (TIPS), highly sterically-hindered organosilane blocking agents, bridged organosilyl protecting groups
- Silylation of Alcohols Employed in Templating Protocols
- Deprotection of Silyl Ethers: general deprotection of silyl ethers procedure, deprotection of 1°, 2°, 3°, aryl, and alkyl silyl ethers, and deprotection of silylene- and disiloxane-protected diols
- Dehydrogenative Silylation of Alcohols and Other Functionalities
- Direct Conversion of Silyl Ethers to Organic Functionality
- Other
- General Silylation Procedures
- Products: Blocking Agents including trimethylsilyl, trialkylsilyl, phenyl-containing, specialty silicon-based, and bridging silicon-based blocking agents
- References
