SiBrid® Diethicone; INCI name: Polydiethylsiloxane
SiBrid® fluids are organic-modified siloxanes that cross the boundaries between organics and silicones. SiBrid® fluids are soluble in most organics and silicones.
Diethicone compared to Dimethicone*
* Typical properties for fluids in the viscosity range of 10-500 cSt
Properties | Diethicone | Dimethicone |
---|---|---|
Surface Tension | 25-28 mN/m | 20-22 mN/m |
Glass Transition, Tg | -139 °C | -121 °C |
Refractive Index | 1.43-1.45 | 1.40-1.41 |
Viscosity | full range | full range |
Organic Compatibility | wide range | slight |
Polydiethylsiloxanes (diethicones) are the first of a series of hybrid silicone polymers without methyl substitution. Analogous in structure to dimethicones, the flexible polymer structure of diethicones allows the manufacture of a wide range of fluid viscosities. The beneficial properties of diethicones include excellent spreading, gas permeability, water resistance, lubricity, and the ability to reduce tack. Diethicone’s tactile properties include a dry feel similar to that of dimethicone but with increased cushion. Diethicones have dramatically broad compatibility with organics compared to dimethicones, allowing formulation with common cosmetic raw materials including many hydrocarbons, esters, waxes, and surfactants. Diethicones overcome the solubility limitations of dimethicones with many surfactants, emollient oils, and both natural and synthetic waxes.
Diethicones, in contrast to dimethicones, wet pigments well. The greater organic character of diethicones allows coated pigments and fillers to disperse more readily in organic vehicles allowing either higher pigment volume concentration at equivalent formulation viscosities or substantially lower viscosities at equivalent pigment loadings.
Diethicone: Pigment Wetting Color Grind Viscosity
Diethicone Physical Properties
polydiethylsiloxane; CAS [63148-61-8]
Feel | Viscosity (cSt) | Density | Refractive Index | Flashpoint (°C) | Molecular Weight | |
---|---|---|---|---|---|---|
SiBrid® DE-12 | Light, dry feel | 15-20 | 0.93 | 1.438 | 125 | 400-500 |
SiBrid® DE-15 | Emollience and cushion | 40-50 | 0.96 | 1.442 | 170 | 500-800 |
SiBrid® DE-23 | Substantivity | 250-350 | 0.99 | 1.447 | 250 | 1,300-2,000 |
SiBrid® Diethicone Solubility
S = Soluble
I = Insoluble
PS = Partially Soluble
SiBrid® Diethicone DE-12 | SiBrid® Diethicone DE-15 | SiBrid® Diethicone DE-23 | Dimethicone | |
---|---|---|---|---|
Cyclopentasiloxane | S | S | S | S |
Dimethicone (10 cSt) | S | S | S | S |
Stearyl Methicone | S | S | PS | S |
Hydrogenated Polydecene | S | S | S | PS |
10% Microcrystalline Wax | S | S | PS | I |
Ozokerite | S | S | PS | I |
Octyldodecyl Stearate | S | S | S | I |
Triisostearyl Citrate | S | S | S | I |
Ethylhexyl Palmitate | S | S | S | S |
Octyldodecanol | S | S | S | S |
Castor Oil | I | I | I | I |
Ethylene-Dimethicone Block Polymer | S | S | S | S |
Solubility of Naturals in SiBrid® Diethicone
S = Soluble
I = Insoluble
SiBrid® Diethicone DE-12 (20 cSt) | Dimethicone DMS-T12 (20 cSt) | |
---|---|---|
Jojoba Oil | S | I |
Butyrospermum Parkii (Shea Butter) | S (hot) | I (hot) |
Olea Europaea (Olive) Oil | S | I |
Natural Vitamin E | S | I |
Helianthus Annus (Sunflower) Seed Oil | S | I |
Theobroma Cacao (Cocoa) Seed Butter | S (hot) | I (hot) |
Euphorbia Cerifera (Candelilla) Wax | S (hot) | I (hot) |
Solubility of UV Absorbers
S = Soluble
I = Insoluble
SiBrid® Diethicone DE-12 (20 cSt) | Dimethicone DMS-T12 (20 cSt) | |
---|---|---|
Octinoxate | S | I |
Avobenzone | 1% | I |
Benzophenone-3 | 2% | I |
Octocrylene | 5% | I |
Leave On Conditioner
INCI Name | Ingredient | Supplier | Weight % |
---|---|---|---|
Phase A | |||
DI Water | DI Water | q.s. | |
EDTA | EDTA | 0.10 | |
Magnesium Aluminum Silicate | Veegum Ultra | Vanderbuilt | 0.30 |
Butylene Glycol | Butylene Glycol | 1.00 | |
DL Pantenol | DL Pantenol | 0.30 | |
Cetearyl Alcohol, Behentrimonium Chloride, Polyquaternium 37 | Jeesperse ICE-T CPCS | Jeen Int. | 3.00 |
Sorbitan Oleate | Sorbitan Oleate | 1.00 | |
PCA Glyceryl Oleate | PCA Glyceryl Oleate | 0.10 | |
Propyl Trisiloxane | Sibrid® Propyl Trisiloxane TM-031 | Gelest | 2.00 |
Amidomethicone, Trideceth-12, Cetrimonium Chloride | Jeesilk 94 | Jeen Int. | 1.50 |
Phenethyltrimethicone | Sibrid® Phenethyltrimethicone | Gelest | 2.00 |
Hydrolized Wheat Protein | Hydrolized Wheat Protein | 0.10 | |
Preservative | Preservative | 1.00 | |
Fragrance | Fragrance | 0.40 | |
Procedure: |
See in Formulary.
Long-Wearing Foundation (Water-in-Silicone)
SiBrid® DE-12 is a light emollient that provides excellent spreading and blending and is also an exceptional vehicle for pigment wetting and dispersion. The Gelest SS treated pigments create a smooth, creamy feel.
INCI Name | Ingredient | Supplier | Weight % |
---|---|---|---|
Phase A | |||
Water | Deionized Water | -- | 49.10 |
Magnesium Sulfate | -- | -- | 0.20 |
Butylene Glycol | -- | -- | 6.00 |
Benzoic Acid | -- | -- | 0.20 |
Phase B | |||
C30-45 Alkyl Cetearyl Dimethicone Crosspolymer | Velvesil 125 | Momentive | 10.00 |
Cyclopentasiloxane | -- | -- | 5.00 |
Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone | KF 6038 | Shin-Etsu | 3.00 |
Polydiethylsiloxane | SiBrid® Diethicone DE-12 | Gelest | 5.00 |
Laureth-7 | Rhodasurf L-790 | Solvay | 0.50 |
Phase C | |||
Titanium Dioxide (&) Trimethylsiloxysilicate | Titanium Dioxide SR | Gelest | 8.00 |
Iron Oxides (&) Trimethylsiloxysilicate | Yellow Iron Oxide SR | Gelest | 1.20 |
Iron Oxides (&) Trimethylsiloxysilicate | Red Iron Oxide SR | Gelest | 0.50 |
Iron Oxides (&) Trimethylsiloxysilicate | Black Iron Oxide SR | Gelest | 0.20 |
Talc (&) Trimethylsiloxysilicate | Talc SR | Gelest | 4.10 |
Polydiethylsiloxane | SiBrid® Diethicone DE-12 | Gelest | 7.00 |
See in Formulary.
Anti-Aging Moisturizing Serum with SPF
This serum has the application feel of a rich moisturizer without a heavy or greasy after feel. Vertasil® Tocopheryloxypropyltrisiloxane TM-VE1 adds emollience and softening benefits. Sibrid® Stearyl Methicone TM-181, with a higher viscosity than caprylyl methicone, contributes to the serum’s lubricious feel while providing a smooth application and weightless feel on skin. SiBrid® Diethicone DE-12 improves spreadability and eliminates tack.
INCI Name | Ingredient | Supplier | Weight % |
---|---|---|---|
Phase A | |||
Stearyl Methicone | SiBrid® Stearyl Methicone TM-181 | Gelest | 8.30 |
Polydiethylsiloxane | SiBrid® Diethicone DE-12 | Gelest | 3.00 |
Tocopheryloxypropyltrisiloxane | SiBrid® Tocopheryloxypropyltrisiloxane TM-VE1 | Gelest | 1.00 |
Polyglyceryl Oleate | -- | -- | 1.00 |
Glycol Distearate | -- | -- | 0.75 |
Magnesium Stearate | -- | -- | 0.75 |
Cetyl PEG/PPG-10/1 Dimethicone | Jeesilc EM90 | Jeen International | 2.00 |
Homosalate | -- | -- | 5.00 |
Octocrylene | -- | -- | 5.00 |
Avobenzone | -- | -- | 3.00 |
Phase B | |||
Water | Deionized Water | -- | q.s. |
Propylene Glycol | -- | -- | 5.00 |
Sodium Chloride | -- | -- | 1.00 |
Water (&) Butylene Glycol (&) Portulaca Oleracea L. Extract | Purslane Extract | SK Bioland | q.s. |
Phase C | |||
Fragrance (Parfum) | Delicate Petals | Premier Specialties | q.s. |
Preservative | -- | Schülke | q.s. |
Procedure: |
See in Formulary.
Trisiloxanes contain a cluster of seven methyl groups which form one of the lowest energy flexible structures known. The structure has been compared to a hydrophobic cloud. By altering the length and polarity of the organic substituent trisiloxanes range from light dry feeling volatile liquids to emollient fluids and super-wetting surfactants (with polar substitution). Alkyltrisiloxanes with 6 to 12 carbons in the organic substituent are light, dry, emollient oils with good organic compatibility, particularly when compared to phenyl trimethicone. They are used to enhance slip and reduce tack in skin care and color cosmetics. Organic and inorganic pigments are readily wetted and dispersed in alkyl trisiloxanes, facilitating use in foundations, eyeshadows, blushes, and lip color.
SiBrid® Caprylyl Methicone TM-081; INCI Name: Caprylyl Methicone
SiBrid® TM-081 Caprylyl Methicone offers an exceptionally light, dry feel combined with excellent spreading qualities. SiBrid® TM-081 is an excellent vehicle for long wearing foundations and eyeshadows. It also performs well as an additive in bath and tanning oils to enhance spreadability and reduce tack in many oil-based formulations.
SiBrid® Lauryl Methicone TM-121; INCI Name: Lauryl Methicone
Lauryl Methicone is similar to TM-081 with reduced volatility and increased pigment wetting properties.
SiBrid® Stearyl Methicone TM-181; INCI Name: Stearyl Methicone
Stearyl Methicone is more lubricious than TM-081 but leaves a smooth weightless feeling on the skin. TM-181 can be used to reduce tack and lend a lighter feel to skin treatment products and liquid foundations.
SiBrid® Trisiloxanes
Product | Viscosity (cSt) | Density | Refractive Index |
---|---|---|---|
SiBrid® Propyltrisiloxane TM-031 | 1-2 | 0.82 | 1.399 |
SiBrid® Caprylyl Methicone TM-081 | 3 | 0.82 | 1.413 |
SiBrid® Lauryl Methicone TM-121 | 5-6 | 0.84 | 1.431 |
SiBrid® Stearyl Methicone TM-181 | 12-13 | 0.83 | 1.433 |
SiBrid® Propyltrisiloxane TM-031; INCI Name: Propyltrisiloxane
SiBrid® TM-031 is a personal care silicone vehicle with solubility and volatility characteristics similar to cyclopentasiloxane (D5). These properties allow formulators to achieve performance needed while addressing regulatory concerns.
Property | TM-031 |
---|---|
Color | Colorless |
Refractive Index | 1.399 |
Organic Compatibility | Yes |
Viscosity (cSt) | 1-2 |
Flashpoint (°C) | 54 |
Boiling Point (°C) | 197 |
SiBrid® TM-031 Benefits:
- Reduces tack and greasiness
- Improves spreadability
- Cleansing properties
- Light and dry skin feel
- Soft and silky after-feel
SiBrid® TM-031 Applications (alternative to D5):
- Tanning oils
- Foundations
- Bath and cleaning products
- Solid sticks
- Hair care products
- Creams and lotions
Solubility of SiBrid® TM-031
1:1 ratios
S = Soluble
I = Insoluble
Cosmetic Ingredient | SiBrid® TM-031 | D5 |
---|---|---|
Dimethicones | S | S |
Diethicones | S | S |
Ethylhexyl Palmitate | S | S |
Hydrogenated Polyisobutene | S | S |
Hydrocarbons | S | S |
Octyl Methoxycinnamate | S | I |
Jojoba Oil | S | S |
Butyrospermum Parkii (Shea Butter) | S | S |
Castor Oil | I | I |
Caprylyl/Capric Triglyceride | S | S |
Isododecane | S | S |
Ethanol | S | S |
Makeup Remover with SiBrid® Propyltrisiloxane TM-031
SiBrid® Propyltrisiloxane TM-031 as a makeup solvent to clean up mascara, eyeliner, and other long-wearing or waterproof eye and face makeups in an instant.
INCI Name | Ingredient | Supplier | Weight % |
---|---|---|---|
Phase A | |||
Water | Deionized Water | -- | q.s. |
Butylene Glycol | -- | -- | 5.00 |
Water/Butylene Glycol/Portulaca Oleracea L. Extract | Purslane Extract | SK Bioland | 0.50 |
FD&C Blue No. 1 | Blue 1 | -- | q.s. |
Preservative | -- | Schülke | q.s. |
Phase B | |||
Propyltrisiloxane | SiBrid® Propyltrisiloxane TM-031 | Gelest | 40.00 |
Fragrance | Sparkling Rose | Premier Specialties | q.s. |
Procedure: |
See in Formulary.
SiBrid® Lauryl Phenylpropylmethicone PM-212; INCI Name: Dodecylmethylsiloxane-2-phenylpropylmethylsiloxane copolymer
SiBrid® PM-212 is a viscous, high refractive index C12 / phenylpropyl modified light amber silicone that gives high luster and shine to lip products. Films formed using SiBrid® PM-212 resist feathering and creeping, allowing the formulation of emollient lip glosses and lipsticks. SiBrid® PM-212 can also be used in skin and sun care products to improve skin adhesion and film forming capability.
Product | Viscosity (cSt) | Density | Refractive Index |
---|---|---|---|
SiBrid® Lauryl Phenylpropylmethicone PM-212 | 1,500 | 0.91 | 1.464 |
Gloss Lipstick
The high refractive index of SiBrid® Lauryl Phenylpropylmethicone PM-212 creates gloss without excessive tack.
INCI Name | Ingredient | Supplier | Weight % |
---|---|---|---|
Phase A | |||
Castor Oil | Crystal O | Vertellus | 8.45 |
Octyldodecanol | Eutanol G | Cognis | 10.00 |
Triisostearyl Citrate | Schercemol TISC | ISP | 20.00 |
Polydiethylsiloxane | SiBrid® Diethicone DE-15 | Gelest | 10.00 |
Laurylphenylpropyl Methicone | SiBrid® Lauryl Phenylpropylmethicone PM-212 | Gelest | 10.00 |
Copernicia Cerifera (Carnauba) Wax | Carnauba Wax | Strahl & Pitsch | 1.50 |
Euphoria Cerifera (Candelilla) Wax | Candelilla | Ross Wax | 7.00 |
Microcrystalline Wax | Microcrystalline Wax 170/180 | Strahl & Pitsch | 3.50 |
Ozokerite | Ozokerite 170/180 | Frank B. Ross | 2.00 |
Preservatives, antioxidants | -- | -- | 0.35 |
Phase B | |||
Castor Oil | Crystal O | Vertellus | 9.00 |
Pigment | -- | -- | 10.20 |
Mica (&) Titanium Dioxide (&) Silica (&) Stearyl Triethoxysilane | Timiron® Splendid Red, SS-treated | EMD Chemicals/Gelest | 8.00 |
See in Formulary.